Isomescaline

Isomescaline
Clinical data
Other names2,3,4-Trimethoxyphenethylamine; 2,3,4-TMPEA; TMPEA-3; 2C-TMA-3; Reciprocal mescaline
Routes of
administration
Oral[1]
ATC code
  • None
Pharmacokinetic data
Duration of actionUnknown[1]
Identifiers
  • 2-(2,3,4-trimethoxyphenyl)ethan-1-amine
CAS Number
PubChem CID
ChemSpider
UNII
ChEMBL
CompTox Dashboard (EPA)
Chemical and physical data
FormulaC11H17NO3
Molar mass211.261 g·mol−1
3D model (JSmol)
  • O(c1ccc(c(OC)c1OC)CCN)C
  • InChI=1S/C11H17NO3/c1-13-9-5-4-8(6-7-12)10(14-2)11(9)15-3/h4-5H,6-7,12H2,1-3H3 Y
  • Key:PVLFQRLVSMMSQK-UHFFFAOYSA-N Y
 NY (what is this?)  (verify)

Isomescaline (IM), also known as 2,3,4-trimethoxyphenethylamine (2,3,4-TMPEA) or as TMPEA-3 or 2C-TMA-3, is a chemical compound of the phenethylamine and scaline families related to the psychedelic drug mescaline (3,4,5-trimethoxyphenethylamine; 2,3,4-TMPEA).[1][2][3] It is one of several possible positional isomers of trimethoxyphenethylamine (TMPEA).[1][2][3] In addition, it is the positional isomer of mescaline in which the methoxy groups on the phenyl ring are located at the 2, 3, and 4 positions instead of at the 3, 4, and 5 positions.[1][2][3]

In his book PiHKAL (Phenethylamines I Have Known and Loved) and other publications, Alexander Shulgin lists isomescaline's dose as greater than 400 mg orally and its duration as unknown.[1][2][3] The compound produced no effects at tested doses of up to 400 mg orally in humans.[1] It was concluded that isomescaline is inactive.[1][3]

The chemical synthesis of isomescaline has been described.[1] Analogues of isomescaline include 2,3,4-trimethoxyamphetamine (2,3,4-TMA; TMA-3; α-methylisomescaline) and the thioisomescaline (TIM) compounds, among others.[1][2][3]

Isomescaline was first described in the scientific literature by L. Clark and colleagues by 1965.[4] Subsequently, it was described in greater detail by Shulgin in PiHKAL in 1991.[1] Isomescaline is not a controlled substance in Canada as of 2025.[5]

See also

References

  1. ^ a b c d e f g h i j k Shulgin, Alexander; Shulgin, Ann (September 1991). PiHKAL: A Chemical Love Story. Berkeley, California: Transform Press. ISBN 0-9630096-0-5. OCLC 25627628.
  2. ^ a b c d e Jacob P, Shulgin AT (1994). "Structure-Activity Relationships of the Classic Hallucinogens and Their Analogs". In Lin GC, Glennon RA (eds.). Hallucinogens: An Update (PDF). National Institute on Drug Abuse Research Monograph Series. Vol. 146. National Institute on Drug Abuse. pp. 74–91. PMID 8742795. Archived from the original on 13 July 2025.
  3. ^ a b c d e f Shulgin AT (2003). "Basic Pharmacology and Effects". In Laing RR (ed.). Hallucinogens: A Forensic Drug Handbook. Forensic Drug Handbook Series. Elsevier Science. pp. 67–137. ISBN 978-0-12-433951-4. Archived from the original on 13 July 2025.
  4. ^ Clark LC, Benington F, Morin RD (May 1965). "The Effects of Ring-Methoxyl Groups on Biological Deamination of Phenethylamines". J Med Chem. 8 (3): 353–355. doi:10.1021/jm00327a016. PMID 14323146.
  5. ^ "Controlled Drugs and Substances Act". Department of Justice Canada. Retrieved 19 January 2026.