2-enoate reductase

2-enoate reductase
Identifiers
EC no.1.3.1.31
CAS no.70712-51-5
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
Gene OntologyAmiGO / QuickGO
Search
PMCarticles
PubMedarticles
NCBIproteins

In enzymology, 2-enoate reductase (EC 1.3.1.31) is an enzyme that catalyzes the chemical reaction of α,β-unsaturated carboxylic acids. Crotonic acid is a typical example:[1]

+ NADH
 
 
H+
 
H+
 
 
+ NAD+
 

The three substrates of this enzyme are crotonic acid, reduced nicotinamide adenine dinucleotide (NADH), and a proton. Its products are butyric acid and oxidised NAD+.[2]

This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-CH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is butanoate:NAD+ Delta2-oxidoreductase. This enzyme is also called enoate reductase. This enzyme participates in phenylalanine metabolism. It has cofactors: flavin adenine dinucleotide and iron–sulfur protein.[1]

References

  1. ^ a b Enzyme 1.3.1.31 at KEGG Pathway Database.
  2. ^ Tischer W, Bader J, Simon H (1979). "Purification and some properties of a hitherto-unknown enzyme reducing the carbon-carbon double bond of alpha, beta-unsaturated carboxylate anions". Eur. J. Biochem. 97 (1): 103–12. doi:10.1111/j.1432-1033.1979.tb13090.x. PMID 477658.