Nontronite
| Nontronite | |
|---|---|
Nontronite from Slovakia | |
| General | |
| Category | Phyllosilicate minerals |
| Group | Smectite group |
| Formula | (Ca0.5,Na)0.3FeIII2(Si,Al)4O10(OH)2·nH2O |
| IMA symbol | Non[1] |
| Strunz classification | 9.EC.40 |
| Crystal system | Monoclinic |
| Space group | C2/m (no. 12) |
| Identification | |
| Color | Yellow, olive-green, green, orange, brown |
| Crystal habit | Earthy masses |
| Cleavage | Perfect basal |
| Fracture | Uneven |
| Mohs scale hardness | 1.5 to 2 |
| Luster | Earthy to dull |
| Streak | Colorless |
| Specific gravity | 2.3 |
| Optical properties | Biaxial (−) |
| Refractive index | nα = 1.530–1.580; nβ = 1.555–1.612; nγ = 1.560–1.615 |
| Birefringence | δ = 0.030–0.035 |
| References | [2][3][4][5] |
Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite.[6][7] Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchangeable cations.
Ignoring the isomorphic substitution of Si by Al, with exchangeable cations compensating for the resulting negative electrical charges and their hydration water in the interlayers, the elemental composition of nontronite could be idealised as simply FeIII2Si4O10(OH)2.[8]
A typical structural formula for nontronite is Ca0.3(FeIII3.5Al0.4Mg0.1)(Si7Al0.8Fe0.2)O20(OH)4·nH2O.[9] The dioctahedral sheet of nontronite is composed mainly of trivalent iron (Fe3+) cations, although some substitution by trivalent aluminium (Al3+) and divalent magnesium (Mg2+) does occur. The tetrahedral sheet is composed mainly of silicon (Si4+), but can have substantial (about 1 in 8) substitution of either Fe3+ or Al3+, or combinations of these two cations. Thus, nontronite is typically characterised by having most (usually greater than 60%) of the layer charge located in the tetrahedral sheet. The layer charge is generally balanced by divalent calcium (Ca2+) or magnesium (Mg2+).
Nontronite forms from the weathering of biotite and basalts, precipitation of iron- and silicon-rich hydrothermal fluids and in deep sea hydrothermal vents.[10][11] Some evidence suggests that microorganisms may play an important role in their formation.[12] Microorganisms are also involved in reduction of structural iron in nontronite when soils undergo anoxia, and the reduced form of the clay appears to be highly reactive towards certain pollutants, perhaps contributing to the destruction of these compounds in the environment.[13][14]
It was named by Pierre Berthier in 1827 from the town of Nontron in the Dordogne department in Nouvelle-Aquitaine in southwestern France, near its type locality.[4]
The only known commercially viable and operational nontronite mine is located in Canterbury, New Zealand. Palmer Resources operates this mine. The finished products are used internationally in industrial applications (pulp & paper, surface coating) and in cosmetics marketed as New Zealand Glacial Clay.[15]
See also
- Saponite – Phyllosilicate mineral in the smectite group
References
- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Nontronite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 28 July 2022.
- ^ Barthelmy, David (2014). "Nontronite Mineral Data". Webmineral.com. Retrieved 28 July 2022.
- ^ a b "Nontronite". mindat.org. Retrieved 28 July 2022.
- ^ Dainyak, Lidia G.; Zviagina, Bella B.; Rusakov, Viacheslav S.; Drits, Victor A. (2006). "Interpretation of the nontronite-dehydroxylate Mossbauer spectrum using EFG calculations". European Journal of Mineralogy. 18 (6): 753–764. Bibcode:2006EJMin..18..753D. doi:10.1127/0935-1221/2006/0018-0753.
- ^ Eggleton, R. A. (1977), Clay minerals, vol. 12, pp. 181–194
- ^ Keeling; et al. (2000). "Geology and Characterization of Two Hydrothermal Nontronites from Weathered Metamorphic Rocks at the Uley Graphite Mine, South Australia". Clays and Clay Minerals. 48 (5): 537–548. Bibcode:2000CCM....48..537K. doi:10.1346/CCMN.2000.0480506. S2CID 129598259.
- ^ Alexandrov, Vitaly; Rosso, Kevin M. (2013-11-07). "Insights into the mechanism of Fe(II) adsorption and oxidation at Fe–clay mineral surfaces from first-principles calculations". The Journal of Physical Chemistry C. 117 (44): 22880–22886. doi:10.1021/jp4073125. ISSN 1932-7447. Retrieved 2025-09-02.
- ^ Gates; et al. (2002). "Mountainville nontronite". Clays and Clay Minerals. 50: 223–239. doi:10.1346/000986002760832829. S2CID 95954306.
- ^ Bischoff (1972), Clays and Clay Minerals, vol. 20, pp. 217–223
- ^ Eggleton, R. A. (1975). "Nontronite topotaxial after hedenbergite". American Mineralogist. 60: 1063–1068.
- ^ Kohler; et al. (1994), Clays and Clay Minerals, vol. 42, pp. 680–701
- ^ Tor, Jason M.; Xu, Caifen; Stucki, Joseph M.; Wander, Michelle M.; Sims, Gerald K. (2000). "Trifluralin degradation under micro-biologically induced nitrate and Fe(III) reducing conditions". Environmental Science & Technology. 34 (15): 3148–3152. Bibcode:2000EnST...34.3148T. doi:10.1021/es9912473.
- ^ Xu, Jennifer C.; Stucki, Joseph W.; Wu, Jun; Kostka, Joel E.; Sims, Gerald K. (2001). "Fate of atrazine and alachlor in redox-treated ferruginous smectite". Environmental Toxicology and Chemistry. 20 (12): 2717–2724. Bibcode:2001EnvTC..20.2717X. doi:10.1002/etc.5620201210. PMID 11764154.
- ^ "New Zealand Glacial Clay Fact Sheet". Palmer Resources Limited.