Gadolinium(III) selenate

Gadolinium(III) selenate
Identifiers
CAS Number	20148-56-5 ;
3D model (JSmol)	Interactive image;
ChemSpider	15008011;
PubChem CID	20432118;
	InChI InChI=1S/2Gd.3H2O4Se/c;;31-5(2,3)4/h;;3(H2,1,2,3,4)/q2*+3;;;/p-6 Key: LSEBDKBNNFPZKP-UHFFFAOYSA-H;
	SMILES [O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-].[O-][Se](=O)(=O)[O-].[Gd+3].[Gd+3];
Properties
Chemical formula	Gd2(SeO4)3
Molar mass	743.395 ; 887.523 (octahydrate)
Density	3.309g/cm3 (octahydrate)
Solubility in water	soluble
Related compounds
Other anions	gadolinium(III) selenite; gadolinium(III) sulfate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Gadolinium(III) selenate is an inorganic compound with the chemical formula Gd₂(SeO₄)₃. It exists as the anhydrate and octahydrate. The octahydrate transforms into the anhydrate when heated to 130 °C.

Preparation

Gadolinium(III) selenate can be obtained by crystallizing from the reaction of gadolinium oxide and selenic acid solution:^[2]^[3]

Gd₂O₃ + 3 H₂SeO₄ → Gd₂(SeO₄)₃ + 3 H₂O

References

^ 化学化工物性数据手册（无机卷）.刘光启等主编.化学工业出版社.16.2 硒酸盐.P₅₆₉
^ Perkovskaya, Yu. B.; Sukhanova, I. M. Rare earth metal selenates. Metody Polucheniya Khimicheskikh Reaktivov i Preparatov, 1967. 16: 120-123. ISSN: 0539-5143.
^ Krügermann, Ina (2002). Oxo-Selenate (IV/IV) der Selten-Erd-Elemente und ihre Derivate (PhD Thesis thesis). Universität zu Köln. p. 48

[hxhg-1] 化学化工物性数据手册（无机卷）.刘光启等主编.化学工业出版社.16.2 硒酸盐.P₅₆₉

[2] Perkovskaya, Yu. B.; Sukhanova, I. M. Rare earth metal selenates. Metody Polucheniya Khimicheskikh Reaktivov i Preparatov, 1967. 16: 120-123. ISSN: 0539-5143.

[3] Krügermann, Ina (2002). Oxo-Selenate (IV/IV) der Selten-Erd-Elemente und ihre Derivate (PhD Thesis thesis). Universität zu Köln. p. 48

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