Flavanone 7-O-glucoside 2"-O-beta-L-rhamnosyltransferase

Flavanone 7-O-glucoside 2"-O-beta-L-rhamnosyltransferase
Identifiers
EC no.2.4.1.236
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
Search
PMCarticles
PubMedarticles
NCBIproteins

Flavanone 7-O-glucoside 2"-O-beta-L-rhamnosyltransferase (EC 2.4.1.236) is an enzyme that catalyzes the chemical reaction

+ UDP-rhamnose
 
 
 
 
 
 
 
+ UDP
 

The two substrates of this enzyme are the flavanone glucoside, prunin, and UDP-rhamnose. Its products are naringin and uridine diphosphate (UDP).[1][2]

This enzyme belongs to the family of glycosyltransferases, specifically the hexosyltransferases. The systematic name of this enzyme class is UDP-L-rhamnose:flavanone-7-O-glucoside 2''-O-beta-L-rhamnosyltransferase. Other names in common use include UDP-rhamnose:flavanone-7-O-glucoside-2"-O-rhamnosyltransferase, and 1->2 UDP-rhamnosyltransferase. Other flavanone 7-O-glucosides can be substrates, including those from hesperetin or based on the flavones luteolin and apigenin.[1][3]

References

  1. ^ a b Enzyme 2.4.1.236 at KEGG Pathway Database.
  2. ^ Bar-Peled M, Lewinsohn E, Fluhr R, Gressel J (1991). "UDP-rhamnose:flavanone-7-O-glucoside-2''-O-rhamnosyltransferase Purification and characterization of an enzyme catalyzing the production of bitter compounds in citrus". J. Biol. Chem. 266 (31): 20953–9. doi:10.1016/S0021-9258(18)54803-1. PMID 1939145.
  3. ^ Peterson JJ, Beecher GR, Bhagwat SA, Dwyer JT, Gebhardt SE, Haytowitz DB, Holden JM (2006). "Flavanones in grapefruit, lemons, and limes: A compilation and review of the data from the analytical literature" (PDF). Journal of Food Composition and Analysis. 19 (Supplement): S74–S80. doi:10.1016/j.jfca.2005.12.009. Archived (PDF) from the original on 2013-04-02. Retrieved 2014-01-24.