Copper(II) stearate

Copper(II) stearate
Names
Other names
  • Copper dioctadecanoate
  • Copper distearate
  • Cupric octadecanoate
  • Cupric stearate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.010.493
EC Number
  • 211-540-3
UNII
  • InChI=1S/2C18H36O2.Cu/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20);/q;;+2/p-2
    Key: PEVZEFCZINKUCG-UHFFFAOYSA-L
  • [Cu+2].[O-]C(=O)CCCCCCCCCCCCCCCCC.[O-]C(=O)CCCCCCCCCCCCCCCCC
Properties
Cu(C17H35COO)2
Molar mass 630.48
Appearance blue-green amorphous substance[1]
Density 1.10 g/cm3
Melting point 112 °C (234 °F; 385 K)[3]
Boiling point 250 °C (482 °F; 523 K)
insoluble[2]
Solubility insoluble in ethanol, ether[2]
soluble in pyridine[2]
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P280, P305, P338, P351
Related compounds
Related compounds
Mercury(II) stearate, Cobalt(II) stearate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Copper(II) stearate is a metal-organic compound, a salt of copper and stearic acid with the formula Cu(C17H35COO)2.[4] The compound is classified as a metallic soap, i.e. a metal derivative of a fatty acid.

Properties

The compound is stable and non-reactive under normal conditions.[5]

When trying to ignite, copper stearate first melts and then begins to burn with a green (at the base) flame, then it quickly turns black due to the formation of cupric oxide:

(C17H35CO2)2 + 5 O2 → CuO↓ + 36 CO2↑ + 35 H2O↑

Synthesis

Copper(II) stearate can be prepared by an exchange reaction involving sodium stearate and copper sulfate:[6]

CuSO4 + 2 C17H35O2Na → Cu(C17H35O2)2↓ + Na2SO4

Uses

Copper(II) stearate is used in the production of anti-fouling paint and varnish materials.

It is also used as a component in casting bronze sculptures[7] and serves as a catalyst for the decomposition of hydroperoxides.[8]

References

  1. ^ "MatWeb - The Online Materials Information Resource". matweb.com. Retrieved 13 February 2023.
  2. ^ a b c Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. pp. 4–62. ISBN 978-1-4822-6097-7. Retrieved 13 February 2023.
  3. ^ Perry, Dale L. (2016-04-19). Handbook of Inorganic Compounds. CRC Press. p. 151. ISBN 978-1-4398-1462-8.
  4. ^ "Copper(II) stearate". Oakwood Chemical. Retrieved 13 February 2023.
  5. ^ "SAFETY DATA SHEET" (PDF). chemservice.com. Retrieved 14 February 2023.
  6. ^ Richardson, H. Wayne (16 January 1997). Handbook of Copper Compounds and Applications. CRC Press. p. 85. ISBN 978-0-8247-8998-5. Retrieved 13 February 2023.
  7. ^ Scott, David A. (2002). Copper and Bronze in Art: Corrosion, Colorants, Conservation. Getty Publications. p. 293. ISBN 978-0-89236-638-5. Retrieved 13 February 2023.
  8. ^ Ugo, R. (6 December 2012). Aspects of Homogeneous Catalysis: A Series of Advances. Springer Science & Business Media. p. 85. ISBN 978-94-010-1199-0. Retrieved 13 February 2023.