1,2-Bis(diisopropylphosphino)ethane

1,2-Bis(diisopropylphosphino)ethane
Names
Preferred IUPAC name
(Ethane-1,2-diyl)bis[di(propan-2-yl)phosphane]
Other names
dippe
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C14H32P2/c1-11(2)15(12(3)4)9-10-16(13(5)6)14(7)8/h11-14H,9-10H2,1-8H3 Y
    Key: RMFRFTSSEHRKKW-UHFFFAOYSA-N Y
  • P(C(C)C)(CCP(C(C)C)C(C)C)C(C)C
Properties
C14H32P2
Molar mass 262.358 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

1,2-Bis(diisopropylphosphino)ethane (dippe) is a commonly used bidentate ligand in coordination chemistry. An efficient synthesis from the parent phosphine oxides has been published.[1]

This compound is similar to the ligand 1,2-bis(diphenylphosphino)ethane (dppe), with the substitution of isopropyl groups for phenyl groups.

References

  1. ^ Doyle, Laurence R.; Heath, Alex; Low, Choon Heng; Ashley, Andrew E. (10 February 2014). "A Convenient Synthetic Protocol to 1,2‐Bis(dialkylphosphino)ethanes". Advanced Synthesis & Catalysis. 356 (2–3): 603–608. doi:10.1002/adsc.201300787.